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Finally, Ill admit to some level of personal bias as well

First-Time Rewards, as the name suggests, are only granted the first time you clear a stage, while Chance Rewards have a possibility of dropping with every victory

GX episode 167: "Thank-You Duel

V & VMAX Cards Are Nearly Equal In Price In The Pokmon TCG Though it might be expected for VMAX cards to sell at a higher price than their lesser V counterparts, the two actually usually sell for the same price, except in a few cases

The YouTuber didn't specify what cards he has in particular, but it's more than likely he has plenty of copies, including multiple copies of the rarest cards in each set